화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터)
권호 16권 2호, p.1213
발표분야 고분자
제목 Synthesis and characterization of ferrous oxide-polymer fiber nanocomposite hybrid adsorbents
초록 Hydrous metal oxides (Fe2O3, MnO, TiO2, Al2O3, ZrO2 and etc) are one of the most important groups of inorganic adsorbents for heavy metal and radionuclide ions. However they are synthesized as fine particles and suffer from further agglomeration. To overcome this technical drawback the fabrication of hybrid adsorbents by direct synthesis of metal oxide nanoparticles onto the surface of polymer matrix is proposed. Polymer matrix is modified by radiation-induced graft polymerization of a monomer with desired functional groups used as precursors of metal oxide nanoparticles with subsequent precipitation of these nanoparticles on the polymer surface. Variation of grafting degree, length and density of grafted chains allows to stabilize nanoparticles against their aggregation and to control their size.
Hydrous ferric oxides-polypropylene fiber nanocomposites were synthesized by using this technique. Coated fibers were analyzed by scanning electron microscopy, energy-dispersive X-ray spectroscopy, x-ray diffraction method. Fiber diameter was on the order of 20 μm, and the observed coating nanoparticles ranged from 20 to 80 nm.
저자 서장현, Bondar Juliia, 조현국, 박정수, 한도흥
소속 영남대
키워드 nanocomposite; hybrid; adsorbents; ferrous oxide-polymer
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