| 학회 | 한국화학공학회 |
| 학술대회 | 2012년 봄 (04/25 ~ 04/27, 제주 ICC) |
| 권호 | 18권 1호, p.1085 |
| 발표분야 | 촉매 |
| 제목 | Photocatalytic Oxidation of Alcohols with Titanium(Ⅳ) Phthalocyanine bridged Periodic Mesoporous Organosilica |
| 초록 | PMOs (Periodic Mesoporous Organosilicas) are considered as one of the promising organic-inorganic hybridized materials due to their various and easy functionality as well as stability with commercially viable synthetic route. Moreover, fluorophore or chromophore such as phthalocyanine can lead a variety of applications. And metallophthalocyanine is even more applicable with high potency. Titanium(Ⅳ) phthalocyanine bridged periodic mesoporous organosilica (TiPC-PMO) was successfully synthesized by co-condensation using bistriethoxysilylethane(BTE) and TiPc-silane under the microwave irradiation. And the TiPC-PMO was demonstrated in the VIS-photocatalytic oxidation of substritute benzyl alcohols by visible light which formed corresponding aldehydes, ketones and/or epoxides with considerably high activities. |
| 저자 | 임청래, 박상언 |
| 소속 | 인하대 |
| 키워드 | Titanium(Ⅳ) Phthalocyanine bridged Periodic Mesoporous Organosilica |
| 원문파일 | 초록 보기 |
