| 학회 |
한국화학공학회 |
| 학술대회 |
2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터) |
| 권호 |
23권 2호, p.1922 |
| 발표분야 |
에너지 환경 |
| 제목 |
Effect of phenyl substitution on electrochemically mediated dechlorination of allyl chloride by Co(I)(bipyridine) in aqueous CTAB solutions |
| 초록 |
Allyl chloride (AC) and its derivatives are prominent environmental contaminants. This work reports electrocatalytic reductive dechlorination of a phenyl-substituted allyl chloride derivative, cinnamyl chloride (CiC), by electrogenerated [Co(I)(bpy)3]+ (where bpy = 2,2’-bipyridine) in environmentally benign CTAB aqueous solutions to examine the effects of phenyl substitution on the dechlorination reaction. Cyclic voltammetry over a range of scan rates and CiC concentrations identified the rate limiting mechanism for Co(I)-catalyzed CiC dechlorination, and estimated the homogeneous electron-transfer rate constant (kcat). |
| 저자 |
문일식, G. Muthuraman, K. Chandrasekara Pillai
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| 소속 |
순천대 |
| 키워드 |
친환경; 고효율
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| E-Mail |
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| 원문파일 |
초록 보기 |
