| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
38권 2호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
Perpendicular Microdomain Orientation in High-Molecular-Weight Block Copolymer Films by Combinational Annealing |
| 초록 |
Directed self-assembly of block copolymer (BCP) thin films is emerging as a potential route for numerous applications to generate templates and scaffolds for the fabrication of nanostructured materials. Fabricating periodic patterns over 100-nm period is directly related to an increase in the molecular weight of BCP. However, the translational ordering of high molecular weight block copolymer is a challenging issue, since it will be disturbed by its extremely limited chain mobility due to highly entangled conformation. In this study, the perpendicular lamellar orientation of high-molecular-weight BCP films was studied by in-situ grazing incidence small angle x-ray scattering (GISAXS), atomic force microscopy (AFM), and scanning electron microscopy (SEM). We demonstrate the rapid evolution of a perpendicular orientation of lamellar microdomain in polystyrene-b-poly(methyl methacrylate) (PS-b-PMMA) films and their confined films by the topographically patterned substrate. |
| 저자 |
구교성1, 최은영1, 김윤근1, 이문규2, 이수미2, 류두열1
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| 소속 |
1연세대, 2삼성디스플레이 |
| 키워드 |
block copolymer; solvent annealing; directed self-assembly
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| E-Mail |
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