학회 |
한국고분자학회 |
학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
권호 |
32권 2호 |
발표분야 |
분자전자 소재 및 소자 기술(분자전자 부문위원회) |
제목 |
Self-Assembled Monolayers of End-Functionalized Poly(3-hexylthiophene) for Organic Thin Film Transistors |
초록 |
End-functionalized regioregular Poly(3-hexylthiophene)s with a low polydispersity were synthesized by the catalyst-transfer polycondensation of Grignard reagents of 2-bromo-3-hexyl-5-iodothiophene using Ni-catalyst, followed by Ni-catalyzed coupling of tetrahydropyran protected 2-(2-thienyl)ethanol. After deprotection by hydrolysis, the hydroxy groups of P3HT were reacted with 3-(triethoxysilyl)propyl isocyanate. Silica substrates were coated with in the solution of the alkoxy silane end-functionalized P3HT. We studied their morphology using atomic force microscopy, and X-ray photoelectrospectroscopy. We fabricated organic thin film transistor (OTFT) with the self-assembled monolayer of P3HT. |
저자 |
김형수, 박지웅
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소속 |
광주과학기술원 |
키워드 |
end-functionalized Poly(3-hexylthiophene); self-assembled monolayers
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E-Mail |
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