화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 38권 2호
발표분야 분자전자 부문위원회
제목 Modulation of Carrier mobility of Diketopyrrolopyrrole and Quaterthiophene containing Copolymer with the Self-assembled Monolayer on Gate Dielectrics of Thin Film transistors
초록 We have fabricated organic thin-film transistors (OTFTs) using diketopyrrolopyrrole (DPP) and quaterthiophene (QT) containing conjugated polymer, P(DPP-alt-QT) as an active layer with chemically modified SiO2 gate dielectrics. The effects of the surface treatment of SiO2 with alkyltrichlorosilanes were investigated on the electric characteristics of OTFTs made of P(DPP-alt-QT). The self-assembled monolayers (SAMs) were elaborated with n-octyltrichlorosilane (OTS) and n-octadecyltrichlorosilane (ODTS) on SiO2 surface. From the electrical measurements, typical I–V characteristics of TFTs were observed. The best field-effect mobility, μ, was determined to be 1.13 and 3.46 cm2 V-1 s-1 for TFTs made of P(DPP-alt-QT) with OTS- and ODTS-treated SiO2 dielectric layer, respectively while the mobility of the device with bare SiO2 was measured to be 0.23 cm2 V-1 s-1, respectively.
저자 엄현아, 신지철, 이태완, 조민주, 최동훈
소속 고려대
키워드 organic semiconductor; self-assembled monolayer; hole mobility; thin-film transistor; diketopyrrolopyrrole; quaterthiophene
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