| 학회 |
한국화학공학회 |
| 학술대회 |
2011년 봄 (04/27 ~ 04/29, 창원컨벤션센터) |
| 권호 |
17권 1호, p.620 |
| 발표분야 |
열역학 |
| 제목 |
Cloud point and vaper-liquid behavior for the poly(2-methoxyethyl acrylate) + supercritical solvents + cosolvents and carbon Dioxide + 2-methoxyethyl acrylate mixtures |
| 초록 |
Experimental cloud-point curves of binary and ternary mixtures for poly(2-methoxyethyl acrylate) [P(2-MEA)] in supercritical carbon dioxide, dimethyl ether (DME) were measured at temperature range of (60 ~ 180)℃ and pressures up to 1991 bar. Cloud-point behavior of those systems were showed in changed of the pressure-temperature (P-T) when solvent content was changed. Experimental data of phase behaviors for 2-methoxyethyl acrylate (2-MEA) in supercritical carbon dioxide was performed at temperature range of (40 ~ 120)℃ and pressure range of 45 ~ 180 bar. The carbon dioxide + 2-MEA systems exhibit type-I phase behavior with a continuous mixture critical curve. The experimental results were modeled with the Peng-Robinson equation of state with two adjustabl parameters. |
| 저자 |
장윤석, 양동선, 윤순도, 변헌수
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| 소속 |
전남대 |
| 키워드 |
supercritical fluid; Poly(2-methoxyethyl aceylate); 2-methoxyethyl aceylate
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| E-Mail |
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| 원문파일 |
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