학회 |
한국고분자학회 |
학술대회 |
2003년 가을 (10/10 ~ 10/11, 부경대학교) |
권호 |
28권 2호, p.181 |
발표분야 |
분자전자 부문위원회 |
제목 |
Photocrosslinked polymer films with high optical transmittance and good thermal stability |
초록 |
We designed and synthesized new photocrosslinking prepolymers bearing both photoreactive acrylate and cinnamate double bond, which may be applied to many applications such as the field of the display technology. The prepolymers are expected to produce the photolithographic pattern with high transmittance and good thermal stability. Chemical structures of the prepared photocrosslinking prepolymers were confirmed by 1H-NMR and FT-IR spectroscopies. We investigated the photocuring kinetics of the prepolymers using FT-IR and UV-Vis spectroscopies, confirming excellent photoreactivity of the polymers. The photocrosslinking prepolymers were dissolved in the appropriate organic solvents with a photoinitiator and one of the red, green or blue pigments. The solution was spin-coated on a glass substrate, resulting in excellent quality of the thin film about 1 mm. The photocrosslinking prepolymer film was exposed by UV light through a quartz photomask and then developed in an appropriate solvent, leading to the excellent photolithographic pattern. We also confirmed superior thermal stability of photocured polymer film through the measurement of TGA and UV-Vis spectroscopy. |
저자 |
임현순1, 이성범1, 이명섭1, 이준영1, 김환건2
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소속 |
1성균관대, 2서경대 |
키워드 |
Photocrosslinked polymer; optical transmittance; thermal stability; photocured polymer
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E-Mail |
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