화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터)
권호 16권 2호, p.2201
발표분야 촉매 및 반응공학
제목 Hydrogen Production from Aqueous-Phase Reforming of Glycerol over Ni basedCatalyst
초록 Aqueous phase reforming(APR) of glycerol over Ni-based catalyst was investigated for the production of hydrogen . The Ni-based catalyst was prepared by an impregnation method, and characterized by N2 physisorption, CO chemisorption, XRD, TPR, SEM and TEM techniques. The APR of glycerol over Ni-based catalyst was successfully carried out in a fixed-bed reactor system under the reaction conditions of low temperature and high pressure. It was found that the conversion of glycerol and selectivity of hydrogen were significantly affected by the amount of the Ni loading. The conversion of glycerol was increased with increasing Ni loading. However, H2 selectivity was maximized which was depending of the amount of Ni loading and LHSV. The catalytic performace for APR of glycerol was compared with those of steam reforming(SR) of glycerol.
저자 조수현1, 허 은1, 이윤주1, 이승환1, 이관영2, 문동주1
소속 1한국과학기술(연), 2고려대
키워드 glycerol; aqueous phase reforming; hydrogen
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