학회 |
한국화학공학회 |
학술대회 |
2014년 가을 (10/22 ~ 10/24, 대전 DCC) |
권호 |
20권 2호, p.2113 |
발표분야 |
촉매 및 반응공학 |
제목 |
Catalytic Dehydrofluorination of 1,1,1,2,3-Pentafluoropropane (HFC-245eb) to Environment-Friendly Refrigerant 1,1,1,2-Tetrafluoropropene (HFO-1234yf) |
초록 |
It is important to produce the environment-friendly refrigerant with lower global warming factors. The dehydrofluorination of 1,1,1,2,3-pentafluoropropane (HFC-245eb) to 1,1,1,2-tetrafluoropropene (HFO-1234yf) was studied using the catalysis. HFO-1234yf is an advanced refrigerant particularly for the automobiles. We confirmed that the conversion of HFO-1234yf was maintained above 60% for at least 30 hours with less deactivation. The surface-fluorinated metal oxide catalysts were prepared by modified sol-gel method and verified as highly dispersed porous catalytic materials. The structures of catalysts were observed using XPS, XRD, and TG. |
저자 |
임서연, 하정명, 김창수, 김홍곤, 안병성, 최재욱, 이현주, 서동진
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소속 |
한국과학기술(연) |
키워드 |
촉매 |
E-Mail |
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원문파일 |
초록 보기 |