화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.2113
발표분야 촉매 및 반응공학
제목 Catalytic Dehydrofluorination of 1,1,1,2,3-Pentafluoropropane (HFC-245eb) to Environment-Friendly Refrigerant 1,1,1,2-Tetrafluoropropene (HFO-1234yf)
초록 It is important to produce the environment-friendly refrigerant with lower global warming factors. The dehydrofluorination of 1,1,1,2,3-pentafluoropropane (HFC-245eb) to 1,1,1,2-tetrafluoropropene (HFO-1234yf) was studied using the catalysis. HFO-1234yf is an advanced refrigerant particularly for the automobiles. We confirmed that the conversion of HFO-1234yf was maintained above 60% for at least 30 hours with less deactivation. The surface-fluorinated metal oxide catalysts were prepared by modified sol-gel method and verified as highly dispersed porous catalytic materials. The structures of catalysts were observed using XPS, XRD, and TG.
저자 임서연, 하정명, 김창수, 김홍곤, 안병성, 최재욱, 이현주, 서동진
소속 한국과학기술(연)
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