화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전))
권호 33권 1호
발표분야 기능성 고분자
제목 Self Polishing Properties of Zinc–based Copolymers with Various Acrylic Monomer Contents for Antifouling Paints
초록 Antifouling paints are used to protect ship and boat hulls from fouling settlements and to improve craft speed by reducing water friction. Since 2003, antifouling paints contained organotin compounds have been banned after demonstrating toxic effects on non-target marine invertebrates. Therefore, tin-free antifouling paints are required in these days. It was found that zinc methacrylate could be leached out into sea water by the ion exchange reaction between zinc in the polymers and sodium in the sea water. In order to investigate influences of resin compositions such as content of zinc methacrylate, hydrophilicity and molecular weight of copolymers, we synthesized the zinc methacrylate copolymers with various monomer compositions. The characterizations of copolymers were done by FT-IR, 1H-NMR and GPC. Leaching rate of self polishing copolymers was determined from the change in thickness of dried films after sea water immersion in a dynamic condition.
저자 정민영, 강태운, 박현, 이인원, 전호환, 조남주
소속 부산대
키워드 Antifouling paint; Marine paint; Self polishing copolymer(SPC); Zinc methacrylate; Tin-free antifouling paint
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