화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 고분자
제목 Synthesis and Properties of Poly(1-ethynyl-2-fluorobenzene)
초록 Poly(1-ethynyl-2-fluorobenzene) was synthesized via the polymerization of 1-ethynyl-2-fluorobenzene by W- and Mo-based catalysts.  The polymerization was proceeded well to give the corresponding polymer in high yield. The electro-optical properties of poly(1-ethynyl-2-fluorobenzene) were measured and discussed. The cyclic voltamograms of the resulting poly(1-ethynyl-2-fluorobenzene) exhibited reversible electrochemical behaviors between the doped and undoped peaks. The kinetics of the redox process of polymer was found to be controlled by the diffusion process from the experiment plotting the oxidation current density of polymer versus the scan rate.
저자 김동우1, 임권택1, 제갈영순2, 박종욱3
소속 1부경대, 2경일대, 3경희대
키워드 1-ethynyl-2-fluorobenzene; conjugated polymer; catalyst; photoluminescence; polymerization; cyclic voltammograms
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