| 학회 | 한국화학공학회 |
| 학술대회 | 2019년 봄 (04/24 ~ 04/26, 제주국제컨벤션센터) |
| 권호 | 25권 1호, p.962 |
| 발표분야 | 촉매 및 반응공학(Catalysis and Reaction Engineering) |
| 제목 | Bifunctional catalyst for selective conversion of syngas into aromatic hydrocarbons |
| 초록 | Aromatics such as benzene, toluene and xylene have mainly produced from petroleum from catalytic reforming or cracking. Obtaining aromatics from non-petroleum feedstocks has been paid attention because of the increase in market demand for aromatics and the depletion of petroleum resources. In this research, bifunctional catalysts combined with K/Fe-Cu-Al and HZSM-5 were developed for the one-step conversion of syngas to aromatics. The C1-C12 range hydrocarbons with high olefin contents from syngas could be firstly produced by FTS over K/Fe-Cu-Al and subsequently converted to aromatic compounds over HZSM-5. It was confirmed that the presence of zeolite can alter the product distribution toward aromatic-rich gasoline range hydrocarbons. Effects of reaction conditions (temperature, pressure and syngas ratio) and catalyst conditions (acidity of ZSM-5, FTS/HZSM-5 catalysts ratio and proximity of the two components) were investigated for obtaining high aromatics yield. |
| 저자 | 박경아, 곽근재 |
| 소속 | 한국화학(연) |
| 키워드 | 촉매 |
| 원문파일 | 초록 보기 |
