화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU))
권호 23권 2호
발표분야 포스터_고분자
제목 Association of acidity in Polyfluorene based-Electrolytes with the Photovoltaic Properties
초록 The interfacial effect on photogenerated holes and electrons transfer is known related with a Schottky barrier and the resistance of device. Herein, we investigated the association of acidity in polyfluorene based-electrolytes (PFN) with the photovoltaic properties, such as the Schottky barrier and the resistance of device. The PFN has been famous, but the association between PFN and acid is rarely investigated. Thus, we selected four materials with different acidity, where the pKa value are from 4.7 to -2.8. The power conversion efficiencies (PCEs) were performed to investigate the effect of acidity. To explain the photovoltaic parameter, especially the short-circuit current density (Jsc) and the fill factor (FF), the Kelvin probe microscopy and the impedence spectroscopy were performed. The result shows well-matched association with the photovoltaic properties, where the high Jsc correspond to the low Schottky barrier and the high FF correspond to the high recombination resistance.
저자 진호철, 정미진, 이준호, Ratna dewi maduwu, sabrina aufar salma, 손동환, 김주현
소속 부경대
키워드 Polyfluorene; Schottky barrier; Photovoltaic properties; Acidity
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