| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
38권 2호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
High-Mobility Air-Stable Naphthalene Diimide-Based Copolymer Containing Extended π-Conjugation for n-Channel Organic Field Effect Transistors |
| 초록 |
A high-performance naphthalene diimide (NDI)-based conjugated polymer for use as the active layer of n-channel organic field-effect transistors (OFETs) is reported. The solution-processable n-channel polymer is systematically designed and synthesized with an alternating structure of long alkyl substituted-NDI and thienylene–vinylene–thienylene units (PNDI-TVT). The material has a well-controlled molecular structure with an extended π-conjugated backbone, with no increase in the LUMO level, achieving a high mobility and highly ambient stable n-type OFET. The top-gate, bottom-contact device shows remarkably high electron charge-carrier mobility of up to 1.8 cm2 V−1 s−1 (Ion/Ioff = 106) with the commonly used polymer dielectric, poly(methyl methacrylate) (PMMA). Moreover, PNDI-TVT OFETs exhibit excellent air and operation stability. |
| 저자 |
김란1, 강일1, 윤희준1, 노용영2, 권순기1, 김윤희1
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| 소속 |
1경상대, 2동국대 |
| 키워드 |
OTFTs; conjugated polymer; air-stability; extended π-conjugation
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| E-Mail |
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