| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
22권 2호 |
| 발표분야 |
환경.에너지_포스터 |
| 제목 |
Synthesis and characterization of Cu(I)-doped MIL-100(Fe) adsorbents for high CO/CO2 separation |
| 초록 |
Cu(I) doping of octahedral MIL-100(Fe) was successfully performed by impregnation and activation. Although MIL-100(Fe) adsorbed CO2 better than CO, Cu(I)@MIL-100(Fe) showed selective CO adsorption compared to CO2 owing to π complexation between CO and Cu(I). Effects of Cu (I) loading concentration, activation temperature, and adsorption temperature upon CO/CO2 adsorption properties were systematically investigated. The adsorption behaviors of CO and CO2 on MIL-100(Fe) and Cu(I)@MIL-100(Fe) were well described by the dual-site Langmuir–Freundlich (DSLF) model. Ideal adsorbed solution theory (IAST) was used to predict adsorption isotherms of equimolar CO and CO2 mixtures and to predict CO/CO2 selectivities as a function of bulk pressure. |
| 저자 |
김진수1, The Ky Vo1, 김정훈2, 문수영2, 장봉준2
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| 소속 |
1경희대, 2한국화학(연) |
| 키워드 |
MOF; MIL-101(Cr); Cu; CO; CO2
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| E-Mail |
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