| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터) |
| 권호 |
36권 1호 |
| 발표분야 |
분자전자용 소재 및 소자 |
| 제목 |
Organic solar cells using low-band gap semiconducting polymers containing a perylene unit as a crystallization inducing group |
| 초록 |
A series of semi-conducting copolymers PFDTBT, PF2DTBT, and their ter-polymers containing perylene units were synthesized using Suzuki coupling polymerization. The resulting polymers were characterized by 1H- and 13C-NMR, elemental analysis, DSC, and TGA. The synthesized polymers were found to be soluble in common organic solvents and are easily spin-coated onto glass substrates, resulting high optical quality thin films without defects. Thermo gravimetric analysis shown the copolymers have high thermal stability, the 5 % degradation temperature was found about 350 °C. Among these six polymers, PFDTBT-5Per and PFDTBT-10Per demonstrates semi-crystallization behavior. Energy levels of the highest occupied molecular orbital (HOMO) were also determined by cyclic voltammetry (CV). Photovoltaic devices were fabricated using the copolymers as the p-type donor and C60-PCBM or C70-PCBM as the electron acceptors. |
| 저자 |
김지훈1, 김희운1, 김윤태1, 신원석2, 윤성철2, 진성호1, 황도훈1
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| 소속 |
1부산대, 2한국화학(연) |
| 키워드 |
photovoltaic; perylene; fluorene
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| E-Mail |
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