화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터)
권호 35권 1호
발표분야 기능성 고분자
제목 A New Polymer Electrolyte Membrane for Direct Methanol Fuel Cells
초록 In order to prepare a novel polymer electrolyte membrane for direct methanol fuel cell, a versatile monomer (vinylbenzyl chloride) having a reactive chloromethyl group, was first grafted onto a poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP) film by a simultaneous irradiation process, and then the prepared poly(vinylbenyzl chloride)-grafted FEP (FEP-g-PVBC) film was converted to the desired membranes, poly(vinylbenyzl sulfonic acid)-grafted FEP (FEP-g-PVBSA) membrane via subsequent chemical treatments. The properties of the resulting FEP-g-PVBSA membrane, such as ion exchange capacity, proton conductivity, water uptake, methanol uptake and methanol crossover were investigated.
저자 경비1, 신준화1, 강성아1, 고범석1, 이연식2, 노영창1
소속 1한국 원자력(연), 2전북대
키워드 VBC; membrane; irradiation; grafting;
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