화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2010년 봄 (04/22 ~ 04/23, 대구 EXCO)
권호 16권 1호, p.694
발표분야 이동현상
제목 Separation of Dye from Water Through Supported Liquid Membrane Extraction Process
초록 Synthetic dye Rhodamine 6G (R6G) and water separation was investigated using blended organic liquids in a supported liquid membrane (SLM) system. Highest R6G distribution coefficient (KD=18) was obtainedat feed pH=1 using pure octyl alcohol (OcOH). For SLM stability improvement, LM blends were prepared composed of OcOH andpolysiloxane liquid poly (phenyl methyl) siloxane (PPMS). Though permeability decreased at optimal blending condition of 1:1 (w/w), SLM longevity was exhibited in contrast to pure OcOH SLM. Equilibrium experiments revealed Langmuir type of dye adsorption. The dye mass transport behavior was elucidated wherein it showed a decrease in overall coefficient (Ko) at increasing feed concentrations. At varied hydrodynamic conditions, improved Ko values up to Re= 10000 was observed. But beyond this condition, SLM stability is compromised due to shear-induced LM losses. Acknowledgement-This work was supported by The National Research Foundation of Korea grant [No. 2009-83876] and Priority Research Centers Program [No. 2009-0093816] funded by the Korea Government, Ministry of Education Science and Technology.
저자 Grace Nisola, 김영희, 한미덕, 정욱진
소속 명지대
키워드 extraction; supported liquid membrane; octanol; polysiloxane
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