| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO)) |
| 권호 |
22권 1호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Electron mediator Cu1+[Ni2+(CN)4]1- degrade CF4 to useful product at electro-scrubber |
| 초록 |
Current methods of CF4 degradation ended up with another kind of greenhouse gas and corrosive side products. This investigation aimed to develop CF4 removal at room temperature with formation of useful product by attempting an electrogenerated Cu1+[Ni2+(CN)4]1- mediator. The electrolysis of bimetallic complex at anodized Ti cathode demonstrated the Cu1+[Ni2+(CN)4]1- formation, which was confirmed by additional ESR results. Then the electrogenarted Cu1+[Ni2+(CN)4]1- used to degrade CF4 in the form of mediated electrochemical reduction (MER). The removal efficiency of CF4 was achieved 95% by this present electroscrubbing process at room temperature. Through the spectral results of online and offline FTIR analyzer either in gas or in solution phase demonstrated that the formed major product during the removal of CF4 by electrogenerated Cu1+[Ni2+(CN)4]1- at electroscrubbing was ethanol (CH3CH2OH). |
| 저자 |
A.G.Ramu, G.MUTHURAMAN, 문일식
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| 소속 |
순천대 |
| 키워드 |
: Bimetallic mediator; Cu1+[Ni2+(CN)4]1-; MER; CF4 degradation; Ethanol formation
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| E-Mail |
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