화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2011년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터)
권호 15권 1호
발표분야 차세대 에너지화학소재의 분자구조/미세배열 제어기술
제목 Effect of ether group on the electrochemical properties of imidazolium compounds
초록 Ionic liquids (ILs) have been considered as a promising alternative electrolyte for their extraordinary properties including high thermal, chemical, and electrochemical stability, high ionic conductivity, negligible vapor pressure, and low flammability. Although imidazolium-based ILs have been extensively studied, the attempts to use these ILs as electrolyte for lithium secondary batteries were not very successful due to the migration of imidazolium cations along with lithium ions as well as to their low cathodic stability for the presence of acidic C-2 hydrogen atom. The cathodic stability of the imidazolium compounds was enhanced by the introduction of ether group on the imidazolium ring for the absence of C-2 hydrogen and their interactions with lithium ions.
저자 이제승1, 구종민2
소속 1경희대, 2한국과학기술(연)
키워드 ionic liquid; electrolyte; lithium seconday battery; ether; cathodic stability
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