| 학회 | 한국화학공학회 |
| 학술대회 | 2017년 봄 (04/26 ~ 04/28, ICC 제주) |
| 권호 | 23권 1호, p.675 |
| 발표분야 | 에너지 환경 |
| 제목 | Effect of different cation containing RTIL on Co2+ redox behavior towards mediator generation |
| 초록 | The Ionic liquids have the both cationic and anionic contained hydrophobic groups naturally having a tendency to solve metal ions that solvation effect may differ with difference cationic or anionic moiety of RTIL. In order to generate suitable mediator, there will be a prior knowledge can be advantageous about suitable cationic or anionic moiety. With this idea, we performed the electrochemical behavior of CoCO3 or Co(ClO4)2 in 1-butyl-3-methylimidazolium bis(trifluoromethyl)sulfonyl imide ([BMIM]NTF2) and N-butyl–N-methylpyrrolidinium bis(trifluoromethyl)sulfonyl imide ([Pyr14]NTF2) by cyclic voltammetry method. The electrochemical parameters and redox properties of Co2+/Co3+ and Co2+/Co1+ were analyzed by effect of scan rate, and different electrodes like Pt, Ti and Graphite. Key words: RTIL, cationic ionic liquid, NTF2- anion, redox behavior, CoCl2, mediator. |
| 저자 | Kannan Karunakaran, G.MUTHURAMAN, 문일식 |
| 소속 | 순천대 |
| 키워드 | 친환경 |
| 원문파일 | 초록 보기 |
