학회 |
한국고분자학회 |
학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
권호 |
37권 2호 |
발표분야 |
고분자합성 |
제목 |
Microwave-Assisted Synthesis of Star-Shaped Poly(2-Hydroxyethyl Methacrylate)-B-Poly(L-Lysine) Copolymers by Ring Opening Polymerization of α-Amino Acid-N-Carboxyanhydrides |
초록 |
A series of synthetic star-shaped polymer bioconjugate hybrid materials consisting of poly(2-hydroxyethyl mathacrylate) (p(HEMA)) and poly(L-lysine) (p(Lys)) are synthesized by combining atom transfer radical polymerization of HEMA with ring opening polymerization of α-amino acid-N-carboxyanhydride. In this study the ring opening polymerization was performed in a microwave oven. In comparison with conventional methods, these polymerizations, proceeded rapidly and were completed within 30 min. The resultant copolymers are characterized using nuclear magnetic resonance and infrared spectroscopic techniques. |
저자 |
신진영1, 김일2
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소속 |
1부산대, 2합성고분자 생물접합 하이브리드 재료산업단 |
키워드 |
Block Copolymers; Atom Transfer Radical Polymerization (ATRP); Ring Opening polymerization (ROP).
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E-Mail |
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