| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터) |
| 권호 |
38권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Synthesis and Properties of Phosphorescent Polynorbornene Copolymer with Iridium(III) and Triarylborane Side Groups |
| 초록 |
Phosphorescent polynorbornene copolymers containing side-chain iridium(III) and triarylborane moieties (P1—P3) were synthesized by the vinyl addition copolymerization of functionalized norbornene monomers using Pd(II) catalyst in the presence of 1-octene chain transfer agent. The catalytic system provides high-molecular-weight copolymers with a controlled incorporation of monomers. While the solution UV/vis absorption and PL spectra show two bands ascribable to each side group in the copolymer, the PL spectra of film exhibit a single band originating from iridium moiety. The details of synthesis and photophysical properties of copolymers will be discussed along with fluoride sensing property. |
| 저자 |
김태원, 홍민생, 이민형
|
| 소속 |
울산대 |
| 키워드 |
Polynorbornene; Copolymer; Iridium Emitters; Triarylborane; PhOLEDs
|
| E-Mail |
|
