화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU))
권호 23권 2호
발표분야 포스터_디스플레이
제목 Synthesis and Electro-Optical Properties of Diazocine Derivatives Substituted with Naphthyl Group in Different Positions
초록 The new diazocine derivatives, 1-DAN and 2-DAN have been successfully synthesized and characterized. 1-DAN and 2-DAN, are different the positions of naphthyl substituted in the anthracene. In the film state, 1-DAN and 2-DAN exhibited absorption in the range of 354 to 402 nm and showed blue photoluminescence (PL) emission at 441 and 450 nm. The PL wavelength of 1-DAN was blue-shifted by 9 nm than that of 2-DAC. This is because the conjugation length is decreased by H atom-H atom repulsion between 1-naphthyl and anthracene. Organic light emitting diode (OLED) device using 2-DAN as emitting layer (EML) showed current efficiency of 1.76 cd/A.
저자 장지윤, 박종욱
소속 경희대
키워드 Anthracene; biazocine; blue materials; EML; OLEDs
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