| 학회 |
한국공업화학회 |
| 학술대회 |
2009년 봄 (04/15 ~ 04/17, 호텔인터불고(대구)) |
| 권호 |
13권 1호 |
| 발표분야 |
석유화학윤활유 |
| 제목 |
Synthesis, Structural Characterization, and Syndiospecific Polymerization Behavior of Monomeric Cyclopentadienyltitanatranes via Fine Tuning in Triethanaolateamine Ligand |
| 초록 |
Since the discovery of the catalytic systems for syndiotactic polystyrene (SPS) in middle 1980s, tremendous advances in the design and synthesis of new titanium complexes have been achieved. Most has focused on the development of catalytic systems based on titanium compounds containing modified Cp ligands. Here we report the synthesis of new titanium complexes possessing fine-tuned tetradentate ligands will be demonstrated. The X-ray structures of new catalysts, their synthetic application for SPS, and their comparison of catalytic activities with known catalysts will be also shown. |
| 저자 |
김정희, 문정희, 문유경, 김영조
|
| 소속 |
충북대 |
| 키워드 |
styrene polymerization |
| E-Mail |
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