| 학회 |
한국화학공학회 |
| 학술대회 |
2014년 가을 (10/22 ~ 10/24, 대전 DCC) |
| 권호 |
20권 2호, p.1804 |
| 발표분야 |
열역학 |
| 제목 |
Phase Behavior of the Ternary Mixture System of biodegradable polymer, Dichloromethane and Carbon dioxide |
| 초록 |
The high-pressure phase behavior of biodegradable polymer (poly(D-lactic acid) (Mw = 359,000), poly(L-lactic acid) (Mw = 312,000)), dichloromethane, and carbon dioxide ternary system was measured using a variable-volume view cell. The experimental temperatures and pressure ranged from 313.15 K to 363.15 K and up to 300 bar as functions of the CO2/dichloromethane mass ratio and temperature, at poly(D-lactic acid) weight fractions of 1.0, 2.0, and 3.0%. The correlation results were obtained from the hybrid equation of state for the CO2-polymer system using the van der Waals one-fluid mixing rule. The three binary interaction parameters were optimized by the simplex method algorithm. |
| 저자 |
권정민1, 김학민1, 신헌용2, 김수현3, 김화용1
|
| 소속 |
1서울대, 2서울과학기술대, 3한국과학기술(연) |
| 키워드 |
. |
| E-Mail |
|
| 원문파일 |
초록 보기 |
