| 초록 |
In this study, we identified the structural characteristics of binary tert-butyl hydroperoxide (TBHP) + gaseous clathrate hydrates. High-Resolution Powder Diffraction (HRPD), 13C solid-state NMR and Raman spectroscopy were used to confirm the structure of binary (TBHP + gaseous) clathrate hydrates. Here, we also investigated the thermodynamic stability of binary (TBHP + gaseous) clathrate hydrates. The experimental data were generated using an isochoric pressure-search method. The dissociation data for (TBHP +gaseous) clathrate hydrates are compared with the other hydrocarbon hydrate and pure gaseous hydrate. |
