화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 분자전자 부문위원회
제목 Efficiency enhancement in polymer gate-dielectric based n-type organic field-effect transistors through modified gold electrodes
초록 The performance enhancement of n-type organic field-effect transistors (OFETs) fabricated on cross-linked polymer gate dielectric, through the use of rubidium carbonate (Rb2CO3) modified gold source and drain electrodes with N,N′-ditridecyl-3,4,9,10-perylenetetracarboxylicdiimide (PTCDI-C13) as n-channel material have been demonstrated. The Rb2CO3 thickness dependence device’s electrical performances have been investigated in detail. The device with 10 Å Rb2CO3 exhibited the best performance, and its mobility was five times higher than that of the device without Rb2CO3. UV-visible, X-ray and ultraviolet photoemission spectroscopy were used to investigate the interface between Rb2CO3 and PTCDI-C13, and we found that charge transfer from Rb2CO3 to PTCDI-C13 occurred, resulting in the reduction of the electron charge injection barrier from the gold electrode. The charge injection mechanism and OFET performance enhancement with Rb2CO3 are discussed in detail.
저자 Amit Kumar1, 표승문2, Akshaya Kumar Palai3, Jaehyuk Kwon4, Seung-Un Park5
소속 1KONKUK Univ., 2Department of Chemistry, 3Konkuk Univ., 4120 Neungdong-ro, 5Gwangjin-gu
키워드 Interface modification; Electron injection mechanism; n-Channel; Organic thin-film transistor
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