화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2014년 가을 (11/12 ~ 11/14, 엑스코(대구))
권호 18권 2호
발표분야 에너지저장변환-포스터
제목 Structural planarity and conjugation effects of novel bi-carbazole derivatives organic dyes for dye-sensitized solar cells
초록 Dye-sensitized solar cells based on Ru-complexes have been achieved fairly high solar energy-to-conversion efficiencies above 12%. Recently, organic dye molecules have been employed as promising alternatives to the Ru-complexes because of potential advantages (high molar extinction coefficient, customized molecular design) for photophysical and photochemical properties, as well as low-cost production. In this work, we demonstrate the synthesis of organic photosensitizing dyes with varying carbazole-based chromophores in a molecule, and used as sensitizers for dye-sensitized solar cells (DSSCs). We found that organic dye with thiophene units exhibited a higher molar extinction coefficient and red-shifted absorption, which leads to an improved light harvesting efficiency. Their photovoltaic properties were measured I-V curves, incident photon-to-current (IPCE) efficiencies and impedance analysis by comparison with that of ruthenium dye in same manufacturing condition.
저자 조효정1, 남정은2, 김대환2, 김효정2, 강진규2
소속 1대구경북과학기술원(DGIST), 2대구경북과학기술원
키워드 di-carbazole dye; DSSC
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