화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터)
권호 25권 2호, p.1656
발표분야 에너지 환경 (Energy and Environment)
제목 SnO2 nanowire grown carbon paper as a functional interlayer
초록 Lithium-sulfur battery has been attracting attention as one of the most promising next-generation rechargeable energy storage devices due to its high energy density, low price and environmental friendliness of sulfur. However, in order to commercialize lithium-sulfur battery, there are still some challenges such as low sulfur utilization, insufficient battery cycle life, and poor rate capability. In this study, SnO2 nanowire grown carbon paper (SnO2@CP) was synthesized via a facile CVD technique and then used as a functional interlayer for lithium-sulfur battery. As an interlayer between the cathode and separator, SnO2@CP showed excellent polysulfide trap efficiency. The lithium-sulfur battery with a SnO2@CP interlayer retains 918mAh/g at the 50th discharge at 0.2C, while the battery with a CP interlayer or without functional layer retains only 778mAh/g and 596mAh/g respectively. The increased cycling performance could be ascribed to the fact that web-shaped SnO2 nanowires can efficiently trap the polysulfide dissolution, and the porous carbon paper can provide enhanced conductivity in the electrode.
저자 안현우1, 김윤곤2, 배재진2, 김예규2, 장대희2, 최준일2, 김원배2
소속 1포항공대, 2포항공대 화학공학과
키워드 에너지 환경
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