화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2007년 봄 (05/11 ~ 05/12, 계명대학교)
권호 11권 1호
발표분야 환경에너지
제목 Studies on the synthesis of organic-funactionalized mesoporous material, MCM-41 for DMFC
초록 Siliceous MCM-41 and various organo-functionalized MCM-41s have been successfully synthesized by co-condensation method with/without the addition of NaF. The results of XRD, FT-IR and TG/DTG analyses show that the organo-functional groups incorporated intosilicate framework of MCM-41 have been stably anchored to the silicate framework even after surfactant extraction and subsequent sulfonation. It also shows that the addition of NaF to synthesis mixture could lead to well-resolved MCM-41 but the incorporation of organo-functional groups could be disturbed by F- anions, especially for vinyl group, enhancing the polycondensation than co-condensation.
저자 박준우, 김영창, 정연준, 정지연, 황지영, 김화중
소속 건국대
키워드 organic-funactionalized MCM-41; NaF; DMFC; protonconductivity; methanol permeability
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