| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
19권 2호 |
| 발표분야 |
촉매_포스터 |
| 제목 |
Microwave mediated synthesis of Porous Porphyrin Polymer: An efficient heterogeneous catalyst for N-H insertion reactions |
| 초록 |
Microwave mediated synthesis provides an efficient one pot approach for synthesis of microporous and hierarchically porous organic polymers in relative short time. Synthesized Porphyrin Porous Organic Polymer (P-POP) exhibited moderate surface area of 681 m2/g and high CO2 adsorption capacities of 9 wt % at 40oC. The synthesized P-POP purely consists of Porphyrin macrocycles and has shown to exhibit excellent activity towards N-H insertion reaction, with highest conversions of 60% with 85% selectivity towards mono insertion product. |
| 저자 |
박상언, 김중조, 임청래, Ranjit Kulkarni
|
| 소속 |
인하대 |
| 키워드 |
Porphyrin; N-H insertion; Porous Organic Polymer
|
| E-Mail |
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