화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터)
권호 34권 1호
발표분야 기능성 고분자
제목 Synthesis and Optical Properties of Phosphine Oxide Substituted with Perfluoroether Acrylate
초록 The polymers for an optical waveguide must meet a number of different demands such as low optical loss at the telecommunication wavelength, adjustable refractive index, thermal and photochemical stability. In this work we have prepared UV-curable organic materials derived from phosphine oxide substituted with perfluoroether-acrylate in order to have low optical loss and high thermal stability. 1H NMR spectroscopy confirmed the successful synthesis of the product. Transparent and stable films were obtained from the product by photo-curing, which was optimized by FT-IR investigation. The cured polymer films showed 1.35 of refractive index, -6.13 × 10-5 of thermo-optic coefficient, 0.0007 of birefringence, and 0.1 dB/cm of optical loss, which were measured by prism coupler at 1550 nm of laser source.
저자 김동욱, 주현경, 강영구, 이창진
소속 한국화학(연)
키워드 Phosphine Oxide; Perfluoroether Acrylate; Optical Loss
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