화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO))
권호 23권 1호
발표분야 콜로이드·계면화학_포스터
제목 Synthesis of methyl methacrylate-based copolymers with high thermal property and low water absorption
초록 Poly(methyl methacrylate) (PMMA) has been used as a transparent material for various optical applications due to its high transmittance. However, PMMA has low thermal properties and high water absorption, which often causes deformations of PMMA-based materials. The deformation significantly decreases the light transmittance, limiting the use of PMMA in various applications. Herein, we synthesized four different series of PMMA-based random copolymers to enhance the thermal properties and reduce the water adsorption (e.g., N-phenyl maleimide, N-cyclohexyl maleimide, allyltrimethylsilane, and 2,2,2-trifluoroethyl methacrylate). Thermal properties were tested by measuring the glass transition temperature, thermal stability and coefficient of thermal expansion. Water absorption was measured through water contact angle. These copolymers are expected to resolve the limitations of conventional PMMA-based materials without the loss of transmittance (~90%).
저자 박진태, 백명진, 최현우, 이동욱
소속 울산과학기술원
키워드 Methyl methacrylate; Glass transition temperature; Thermal stability; Coefficient of thermal expansion; Water contact angle
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