| 학회 | 한국화학공학회 |
| 학술대회 | 2010년 봄 (04/22 ~ 04/23, 대구 EXCO) |
| 권호 | 16권 1호, p.978 |
| 발표분야 | 촉매 및 반응공학 |
| 제목 | Steam Reforming of Decahydronaphthalene over Ca modified Ni-based Hydrotalcite Catalyst |
| 초록 | Hydrogen is an ideal fuel because it is clean and simplifies the system integration. But infrastructures for hydrogen supply have not yet been established. For the mobile or stationary production of hydrogen, reforming of hydrocarbons is a practical method.Diesel has higher gravimetric and volumetric hydrogen density than LNG or LPG and well-estabilished delivery infrastructure. In spite of these advantages, reforming of diesel has not been widely studied because of some problems such as severe coke formation, sulfur poisoning, etc. In the study, steam reforming(SR) of decahydronaphthalene(Decalin; C10H18), which is a representative major component of diesel was investigated in a fixed-bed reactor system with the Steam/C ratio of 3,Gas Hourly Space Velocity(GHSV) of 10,000 h-1 at the temperature range from 973 K to 1173 K by employing Ca modified Ni-based hydrotalcite catalysts (CaxNiMg/Al; x=0.01~1). Decalin was fully converted above 973 K with no condensable products.It was found thatCaxNiMg/Al was maintained its catalytic activityduring58 h operation. Catalysts before and after SR were characterized by XRD, TEM, TPR and CO pulse chemisorption. |
| 저자 | 김소정1, 이승환2, 이윤주3, 이상득2, 남석우4, 문동주1 |
| 소속 | 1KIST 청정에너지센터 / UST 청정연료 화학공학, 2KIST 청정에너지센터, 3KIST 청정에너지센터 / 고려대, 4KIST 연료전지센터 |
| 키워드 | hydrogen; steam reforming; decalin; diesel |
| 원문파일 | 초록 보기 |
