| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터) |
| 권호 |
36권 2호 |
| 발표분야 |
유기전자소자용 소재 및 소자(분자전자소재 부문위원회) |
| 제목 |
Synthesis and Characterization of Green Light-emitting Electrophosphorescent Polymers with Different Triplet Energy Main Chain |
| 초록 |
Three series of new green iridium light-emitting electrophosphorescent polymers with fluorene and carbazole as triplet energy main chain have been synthesized via Yamamoto polymerization. The molecular structures of the polymers were characterized with 1H NMR spectroscopy and their photophysical, electrochemical and electroluminescence properties were investigated. Light-emitting devices using the polymers as emitting layers were fabricated with ITO/PEDOT:PSS/polymer/BmPyPB/LiF/Al configurations. More efficient Forster energy transfer from host to iridium complex guest happened with increasing the ratio of the iridium complex in the copolymers. In this series of copolymers, external quantum efficiency of 0.67, a maximum luminous efficiency of 1.24 cd/A and a maximal luminance of 615.2 cd/m2 were observed. |
| 저자 |
XU FEI1, 황도훈2, 황주현3, 이정익3
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| 소속 |
1부산대, 2부산대 화학관, 3한국전자 통신(연) |
| 키워드 |
fluorene; carbazole; iridium complex; Electrophosphorescent
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| E-Mail |
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