화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 봄 (04/12 ~ 04/13, 제주 ICC)
권호 32권 1호
발표분야 기능성 고분자
제목 Synthesis of Novel Water-Soluble Polyfluorene Derivatives and Application to Single Component Non-Volatile Memory Devices
초록 Water solubility of conjugated polymers may offer many applications. Potential applications of water-soluble conjugated polymers include the light-emitting diode and bio- or chemo-sensors. We synthesized neutral polyfluorene derivatives containing bromo-alkyl terminal groups by the palladium catalyzed Suzuki coupling reaction. Bromo-alkyl terminal groups in neutral polyfluorenes were quaternized by trimethyl amine solution. The characterization, optical and electrochemical properties of novel cationic water-soluble polyfluorene derivatives are discussed. Non-volatile memory devices were fabricated by spin-coating using novel water-soluble polyfluorene derivatives, which were used as an active layer. We also investigated the device performance of single component non-volatile polymer memory devices using these polymers. Operating voltage was from -3.0 to 4.0, on/off current ratio between on- and off- state was about 3 orders of magnitude and was not reduced during one thousand cycles.
저자 오승환, 김태욱, 이탁희, 김동유
소속 광주과학기술원
키워드 water-soluble; Memory device; conjugated polymer
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