화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2013년 봄 (04/24 ~ 04/26, 광주 김대중컨벤션센터)
권호 19권 1호, p.607
발표분야 열역학
제목 Synthesis of polyaniline in compressed CO2 and electrochemical properties of polyaniline/reduced graphene oxide hybrid for supercapacitor electrode
초록 Polyaniline has been synthesized through the polymerization of aniline in compressed CO2 without any template and used as a base material for the preparation of polyaniline/reduced graphene oxide (PANI/rGO) hybrid. The PANI/rGO with a mass ratio of 10:1 was prepared by the reduction of graphene oxide using hydrazine under acidic condition. And the PANI/rGO was used as a supercapacitor electrode in order to show the applicabilities of this hybrid material to energy storage devices. The properties of PANI/rGO hybrid was analyzed using scanning electron microscopy (SEM), thermogravimetric analysis (TGA), x-ray diffraction (XRD) and x-ray photoelectron spectroscopy (XPS) methods. Electrochemical performances of PANI/rGO as a supercapacitor electrode were also evaluated.  Cyclic voltammogram (CV) showed excellent redox stabilities at various scan rates. And PANI/rGO hybrid revealed good cycle stabilities even after several thousand cycles and showed high values of specific capacitance.  
저자 신비오, 김선욱, Quoc Minh Pham
소속 울산대
키워드 polyaniline; graphene oxide; supercapacitor electrode
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