화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터)
권호 16권 2호, p.2176
발표분야 촉매 및 반응공학
제목 Long term activity test of iron based catalysts in CSTR
초록 Fischer-Tropsch synthesis (FTS) was carried out using iron based catalytsprepared by co-precipitation andincipient wetness method. Supported iron based catalysts activity were comparedwith that ofthe catalystprepared by conventional co-precipitation method. The reaction was carried out in a continuous stirred tank reactor (CSTR)withvolume of 500cc at 250oC and 25atm using synthesis gasof H2/CO ratio 1 as a simulated feedstock produced from thecoal gasifier. Simulated distillation (SIMDIS) analysis method was used to determine the products distribution. The catalysts physical and chemical properties were analyzed by BET, SEM, PSA, XRD and H2-TPR. Supported iron based catalysts had spherical morphology with particle size of 10~70um, while the co-precipitated spray-dried catalyst was in the range 0f 20~120um. Supported iron based catalysts showed comparable activity in contrast to that of prepared from conventional co-precipitated method. Supported catalysts were expected to have betterattrition strength when used in commercial reactor such as slurrybubble column reactor.
저자 김종건1, 김학주2, 천동현2, 이호태2, 양정일2, 양정훈2, 정 헌2
소속 1충북대, 2한국에너지기술(연)
키워드 Fischer-Tropsch; Synthesis gas; Iron-Based Catalyst
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