화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2006년 봄 (04/06 ~ 04/07, 일산킨텍스)
권호 31권 1호
발표분야 고분자 가공/블렌드
제목 Preparation and Characterization of PP/Organoclay Nanocomposites with Maleic-anhydride
초록 Polypropylene (PP)/organoclay nanocomposites were prepared via a melt-mixing through two-step melt compounding in a co-rotating intermeshing twin screw extruder. Different amounts of maleic anhydride grafted polypropylene (PP-g-MA) were adopted during compounding as a compatibilizer. Structural investigations via X-ray diffraction (XRD) and transmission electron microscopy (TEM) revealed the intercalated morphology of the nanocomposites. The use of PP-g-MA led to not only good clay dispersion but also heterogeneous intercalation. Thermal degradation of the PP nanocomposites was studied by thermogravimetric analysis (TGA). Rheological properties of the PP/organoclay nanocomposites were also investigated via a rotational rheometer in which linear viscoelastic measurements were performed in oscillatory shear with small strain amplitude. Storage (G’) and loss (G”) moduli were found to be decreased at all frequencies with increasing maleic anhydride contents.
저자 이형민, 최형진
소속 인하대
키워드 polypropylene; organoclay; nanocomposite; polypropylene-graft-maleic anhydride
E-Mail