| 학회 |
한국고분자학회 |
| 학술대회 |
2004년 가을 (10/08 ~ 10/09, 경북대학교) |
| 권호 |
29권 2호, p.152 |
| 발표분야 |
고분자 합성 |
| 제목 |
Atom transfer radical polymerizations of N-isopropylacrylamide |
| 초록 |
Transition metal halide compounds are well-known as catalysts for atom transfer radical polymerization (ATRP). Copper halide-amine complexes have been utilized for polymerization of vinyl monomers. However, it has been known that the ATRPs of most polar monomers are not quantitatively achieved in organic solvent at relatively high temperature. Especially, Copper-mediated polymerization of acrylamide should be carefully tuned because of side reaction. In this lab, poly(N-isopropylacrylamide) exhibiting the LCST behavior was successfully prepared by copper halide/alkyl halide-mediated polymerization in aqueous media. We will discuss the results in this presentation. |
| 저자 |
김지희1, 최규진1, 이선배1, 박준형1, 이철한1, 김광웅1, 곽순종1, 홍순만1, 황승상1, 김정안1, 임승순2
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| 소속 |
1한국과학기술(연), 2한양대 |
| 키워드 |
ATRP; N-isopropylacrylamide
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| E-Mail |
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