화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 유기전자소자용 소재 및 소자(분자전자소재 부문위원회)
제목 Synthesis and Properties ofPoly(dithiophene) Derivative for Photovoltaic Cells and Organic Thin Film Transistors.
초록 Importance of development of the polymer solar cell (PSC) have attracted wide attention due to low cost and flexibility in large-area applications. At present, due to the good performance of conducting polythiophenes, a great deal of effort has been devoted to the optimization of solar cells using new thiophene architectures. So, in this study, we designed a new p-type thiophene based copolymer PDTBT, PDTBTT with polycyclic aromatics based thiophene unit to enhance π-conjugation. PDTBT and PDTBTT was synthesized by Stille coupling reaction with high overall yields. The obtained PDTBT and PDTBTT polymers were characterized by elemental analysis, 1H-NMR, UV-absorption and cyclicvoltammetry (CV) studies. The higher thermal stability of this polymer was determined using the thermogravimetric analysis (TGA) and differential scanning calorimeter (DSC)studies. The detailed optical, electronic properties, OTFTs and PSCs device characterizations will be discussed in detail.
저자 장재완1, 안태규2, 차효정2, 하종진1, 박찬언2, 김윤희1, 권순기1
소속 1경상대, 2포항공과대
키워드 OPV; OTFT; OFET; solar cells; organic transistors
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