| 학회 | 한국공업화학회 |
| 학술대회 | 2021년 봄 (05/12 ~ 05/14, 부산 벡스코(BEXCO)) |
| 권호 | 25권 1호 |
| 발표분야 | 포스터-정밀화학 |
| 제목 | Graphitic Carbon Nitride (g-C3N4) as a Heterogeneous Photocatalyst for Decarboxylative Fluorination |
| 초록 | Heterogeneous photocatalyst has gained much attention in photocatalysis field as a sustainable strategy for utilizing solar energy to chemistry. As compared to traditional photoredox chemistry by molecular catalysts, it has great merit due to its recyclability, and stability. Among other semiconductor photocatalysts, graphitic carbon nitride (g-C3N4) has attracted much attention for recent decades due to its mild band gap which corresponds to visible light range. Whereas light-mediated water splitting, H2 evolution and N2 fixation are successfully reported using g-C3N4, there remains a need for applying this heterogeneity to organic synthesis for fine chemicals. Herein, photocatalyzed decarboxylative fluorination was conducted in mild condition using g-C3N4. Photocatalytic activity of g-C3N4 in this reaction was confirmed and the reaction condition showed as optimal with the use of proper solvent and base. |
| 저자 | 김수민, 곽민준, 최현우, 유동원 |
| 소속 | 서울대 |
| 키워드 | Photocatalysis; Heterogeneous photocatalyst; Carbon nitride; Fluorination |
