| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center)) |
| 권호 |
21권 1호 |
| 발표분야 |
촉매 |
| 제목 |
CuSe2 as Cheap and Active Species for Reductive Carbonylation of Nitroarenes to Urethanes |
| 초록 |
Carbamates have been widely used due to their versatilities. The conventional process for the production of carbamates involves the toxic usage of phosgene. Therefore, the reductive of carbonylation of aromatic nitro compounds with carbon monoxide in the presence of alcohols has attracted much attention as a phosgene-free alternative route. Recently, several catalyst systems have been reported. However, these systems involve the usage of costly transitional metal as well as the use of co-catalyst, resulting in many difficulties in recycling the catalyst systems. In our continuous efforts to develop efficient single catalyst for the reductive carbonylation reaction, CuSe2 and CuSe2/Support have been developed as cheap and active heterogeneous catalyst for this aim. The structure, morphology, and crystallography of CuSe2 were investigated by SEM, XRD and XPS. |
| 저자 |
Tran Anh Vy1, Huynh Nguyen Thuy Tram2, Nguyen Thanh Tung1, 김용진2
|
| 소속 |
1Graduate School, 2Korea Univ. of Science and Technology (UST) |
| 키워드 |
carbamate; reductive carbonylation; copper selenide
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| E-Mail |
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