화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU))
권호 20권 2호
발표분야 에너지저장변환_포스터
제목 Preparation of Anion Exchange Membrane based on Poly(phenylene  Oxide) for Vanadium Redox Flow Battery
초록 A polyphenylene oxide (PPO)-based anion exchange membrane based on the functionalization  of bromomethylated PPO using 1-methylimdazole was fabricated for vanadium redox flow application. The imidazolium-bromomethylated PPO (Im-bPPO) showed lower permeability of VO2+ ions (2.9×10-14 m2/sec), compared to Nafion 212 (2.3×10-12 m2/sec) and FAP-450 (7.9×10-14 m2/sec). Even though the Im-bPPO membrane has higher permeability, the energy efficiency of the VRFB with the Im-bPPO membrane was  slightly lower than that of Nafion and FAP-450. The Im-bPPO membrane exhibits good voltage efficiency compared to FAP-450 and Nafion 212 because of its better ion conductivity. The Im-bPPO membrane showed up good performance, but a decline in performance at later cycles was observed.
저자 임민화, 박미정, 문건오, 노현준, Pham Tan Thong, SADHASIVAM THANGARASU, 정호영
소속 전남대
키워드 Vanadium Redox Flow Battery; Anion Exchange Membrane; Poly(phenylene oxide) (PPO)
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