화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 유기전자소자용 소재 및 소자(분자전자소재 부문위원회)
제목 Photovoltaic performance of bifunctional low band gap conjugated copolymer
초록 It has been investigated the bifunctional properties using ambipolar low-band gap conjugated copolymer in organic bulk-heterojunction (BHJ) solar cells. Ambipolar copolymer, poly[3,6-dithien-2-yl-2,5-di(2-decyltetradecanyl)-pyrrolo[3,4-c]pyrrole-1,4-dione-5’,5’’-diyl-alt-benzo-2,1,3-thiadiazol-4,7-diyl] (PDTDPP-alt-BTZ), successfully works as the bifunctional material acting as both donor or acceptor. However, because of fast recombination nature and broken charge balance of hole and electron, solar cell performances were significantly limited. The results indicate that having distinct role of each component might be better for the high performance BHJ solar cells rather than bifunctional property based on good charge transport properties of both hole and electrons.
저자 윤명희1, 이정훈1, 양창덕1, 조신욱2, 김진영1
소속 1울산과학기술대, 2울산대
키워드 ambipolar; organic solar cells
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