| 학회 |
한국화학공학회 |
| 학술대회 |
2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스)) |
| 권호 |
10권 2호, p.2340 |
| 발표분야 |
촉매/반응공학 |
| 제목 |
Highly reactive and enantioselective hydrolytic kinetic resolution of terminal epoxides using new chiral (salen) Co: AlCl3 complex |
| 초록 |
A wide variety of highly selective asymmetric reactions catalyzed by chiral (salen) metal complexes have been disclosed over the past decade. The solvent free hydrolytic kinetic resolution (HKR) of terminal epoxides catalyzed by a new chiral (salen) Co: AlCl3 complex is described. The catalyst shows high reactivity and selectivity in good yields of ＞ 98 % ee under ambient condition within 1 h. |
| 저자 |
Thakur Santosh Singh, 김건중
|
| 소속 |
인하대 |
| 키워드 |
hydrolytic kinetic resolution; asmmetric ring opening; chiral catalyst
|
| E-Mail |
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| 원문파일 |
초록 보기 |
