화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터)
권호 36권 1호
발표분야 분자전자용 소재 및 소자
제목 Synthesis and Characterization of Thienothiophene Derivative for Organic Solar Cell
초록 A thienothiophene based polymer (PONTET) for organic solar cell was synthesized by Suzuki coupling reaction. The structure of PONTET was confirmed by 1H NMR and FT-IR. The thermal, optical and electronic properties of PONTET was investigated by themogravimetric analysis (TGA), differential scanning calorimetry (DSC), UV-vis absorption, photoluminescence spectroscopies, cyclic voltammetry (CV). The absorption maximum spectra of PONTET was observed at 547 nm in solution state and at 637 nm in film state. The PL maximum spectra of PONTET was observed at 619 nm in solution state and at 732 nm in film state. The decomposition temperature of PONTET, which correspond to 5% weight loss upon heating, is around 282 ℃ and glass transition temperature is around 93 ℃. PONTET has narrow band gap as 1.55 eV and shows 1.3 % of power conversion efficiency.
저자 신민기1, 김슬옹1, 차효정2, 황문찬1, 이동희1, 박찬언2, 김윤희1, 권순기1
소속 1경상대, 2포항공과대
키워드 Organic solar cell; OPV; Thienothiophene
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