| 학회 |
한국고분자학회 |
| 학술대회 |
2003년 가을 (10/10 ~ 10/11, 부경대학교) |
| 권호 |
28권 2호, p.203 |
| 발표분야 |
고분자 합성 |
| 제목 |
The reactivity ratios of vinyl type polar monomersin their atom transfer radical copolymerizations. |
| 초록 |
Transition metal-mediated radical polymerization called as atom transfer radical polymerization(ATRP) of vinyl monomers may produce the corresponding well-defined polymers via a controlled/'living' mechanism. However, ATRP of polar vinyl monomers can not be performed effectively due to a side reaction arising from a deactivation of the active site of the transition metal by polar group. We have developed a new process to polymerize polar vinyl monomers such as N-isopropylacrylamide(NiPAM) in aqueous phase using transition metal-mediated radical (co)polymerization. In this presentation, we will report the results for the reactivity ratios of NiPAM and other vinyl monomers in ATRP in aqueous media.
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| 저자 |
김지희1, 최규진1, 이선배1, 박준형1, 김광웅1, 김정안1, 임승순2, 김상섭3
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| 소속 |
1한국과학기술(연), 2한양대, 3LG화학 |
| 키워드 |
reactivity ratio; ATRP; copolymerization
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| E-Mail |
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